Thermochemistry of 1,3,3-Trinitroazetidine and 1,1-Diamino-2,2-dinitroethylene

摘要：

　　Calorimetry was used in the investigation of the thermochemistry of 1,3,3-trinitroazetidine (TNAZ) and 1,1-Diamino-2,2-dinitroethylene (DADNE).The constant-volume combustion energy △cUof TNAZ and DADNE were determined as (-1866.76±0.85)kJ·mol-1 and (-1249.77±0.50) kJ·mol-1 at 298.15K, and the standard combustion enthalpies, △cHθm, were calculated as (-1856.84±0.85) kJ·mol-1 and (-1242.33±0.50) kJ·mol-1, the standard enthalpies of formation, △fHθm, as (-104.65±0.94) kJ·mol-1 and (-116.35±0.60) kJ·mol-1, respectively.

关键词： 1,3,3-Trinitroazetidine(TNAZ) 1,1-Diamino-2,2-dinitroethylene(DADNE) Thermochemistry Constant-volume combustion energy Standard enthalpy of formation

作者: Ji-zhen LI Qiu-fan TANG Bei QU Ya-jun ZHANG Xue-zhong FAN Xiao-gang LIU Sheng-li GAO Xu-wu YANG

作者单位: Department 3, Xian Modern Chemistry Research Institute, Xian, 710065, Shaanxi, China Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University

会议类型: 国际会议

会议名称: 2018 International Conference on Defence Technology (2018国际防务技术会议)

会议地点: 北京

会议语种:英文

页码: 149-151

在线出版日期: 2018-10-21（万方平台首次上网日期，不代表论文的发表时间）