Study on thermal hazard of 3,4-Bis(3-nitrofurazan-4-yl)furoxan(DNTF) by using accelerating rate calorimeter(ARC)

摘要：

　　Thermal decomposition of melted 3,4-bis(3-nitro-furazan-4-yl)furoxan(DNTF) in near adiabatic environment was investigated by using accelerating rate calorimeter (ARC).By the experimental results, kinetic parameters of exothermic reaction of DNTF under adiabatic condition was calculated.The thermal hazard parameters, such as the initial decomposition temperature, the adiabatic temperature rise and the maximum temperature rise rate were obtained through the correction using the thermal inertia factor The adiabatic experiment reveals that DNTF has a relative high initial exothermic decomposition temperature, which is 180.7 ℃.The Ea and A were 197.54 kJ/mol and 7.68×1016 s-1.SADT of DNTF was 203.73 ℃.The 5-second delay exploding point calculated is 313.67 ℃, which is constant with the data obtained by the traditional Woods alloy bathy method.

关键词： DNTF Thermal hazard Accelerating rate calorimeter SADT

作者: Guang-yuan ZHANG De-qiu WANG Qing-hai SHU Bo ZHANG Xue-bin YANG

作者单位: China Ordnance Society, Gansu Yinguang Chemical Industry Group.Co.LTD, Gansu, China School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

会议类型: 国际会议

会议名称: 2018 International Conference on Defence Technology (2018国际防务技术会议)

会议地点: 北京

会议语种:英文

页码: 269-273

在线出版日期: 2018-10-21（万方平台首次上网日期，不代表论文的发表时间）