Recent Progress in Improving Fire Retardancy of Polymers Via Combined Catalysis: Polycarbonate by the Combination of Nanosized Carbon Black and Ni2O3
Catalyzing carbonization of polymer itself to form a protective carbonaceous layer has attracted tremendous interest in the flame retardancy of polymers.In this study, the combined catalyst (nanosized carbon black (CB) and Ni2O3), was found to efficiently catalyze the carbonization of polycarbonate (PC), resulting in greatly improved its flame retardancy.The LOI was 31.2%, and UL-94 reached to V0, as well as the PHRR reduced approximately 50%.The flame retardancy mechanism was attributed to the synergistic effect of the combined catalysts on catalyzing carbonization of PC, which could enhance the carbon skeleton of PC to form better carbon layer structurc with small closed-cells, resulting in drastically enhanced barrier effect.
Xin Wen Dongsheng Wang Xuecheng Chen Jie Liu Jiang Gong Tao Tang
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
国际会议
杭州
英文
15-16
2018-06-14(万方平台首次上网日期,不代表论文的发表时间)