Detection of lead Using Thioglycolic Acid Capped ZnSe and ZnSe@ZnS core-shell Quantum Dots
Herein,we proffer a sensitive and selective sensor using ZnSe and ZnSe@ZnS quantum dots(QDs),for detection of toxic metal ions at nm level.It has been found that the TGA capped ZnSe and ZnSe@ZnS QDs were apparently sensitive to Pb2+ions as perceptible from their fluorescence quenching measurements.However,in case of few common heavy metal ions such as Zn2+,Co2+,Fe2+,,Mg2+,Cu2+,Ni2+and Cd2+ions,negligible quenching compared to Pb2+ions was noted.Hence,we have successfully detected Pb2+ions in aqueous solutions based on the photoluminescence(PL)spectroscopy.The observed linearity range was from 10 NM to 100 nM for both Pb2+ions.An alternative QD based sensor for the spectroscopic detection,and concentration quantification of Pb2+ions is proposed.Keywords: Quantum dots,Photoluminescence,Metal ions,Thioglycolic acid,Core-shell QDs.
Irshad Ahmad Mir Qixiao Lu Yuelin Xie Ling Zhu Xinzhong Wang
Shenzhen Key Laboratory of Flexible Memory Materials and Devices,College of Electronic Science and T School of Electronic Communication and Technology,Shenzhen Institute of Information Technology,Shenz
国际会议
上海
英文
1-4
2018-12-17(万方平台首次上网日期,不代表论文的发表时间)