Effects of Charge Compensators on Structure and Luminescent Properties of Microwave Synthesized CaMoO4∶Eu3+ Red Phosphors
Red phosphors CaMoO4∶Eu3+ were synthesized by microwave method with MnO2 as microwave absorbent.The phase structure and luminescent properties of the as-synthesized phosphors were investigated by X-ray powder diffraction and Fluorescence spectrophotometer.The results show that when the reaction time was 40 min, microwave power was medium-high fire (~560 W), we got the tetragonal CaMoO4∶Eu3+ pure phase.The excitation spectrum of CaMoO4∶Eu3+ was composed by a broad band between 200 nm and 350 nm and a series of peaks from 350 nm to 500 nm.The main peak was at 305 nm.The emission spectrum was composed of a series of peaks in the range of 550~750 nm and the main peak was at 617 nm due to the 5D0→7F2 transition of Eu3+.Doping charge compensator Li+, Na+ or K+ could improve the luminous intensity of the sample.When the doping amount of Li+, Na+ or K+ were 8 mol%, the luminous intensity of the sample reached the maximum.The intensity of the emission peak at 617 nm was 4.04, 3.42, 3.48 times of sample without doping charge compensator.
Microwave method CaMoO4∶Eu3+ Red phosphors Charge compensator
Ying Han Zhi-lin Li Wan Zhang Yan-jie Yin Yan-mei Li Li-li Wang Yong-qing Zhai
College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
国际会议
The 2016 China Functional Materials Technology and Industry Forum (2016中国国际功能材料大会暨第九届中国功能材料及其应用学术会议)
重庆
英文
592-597
2016-07-25（万方平台首次上网日期，不代表论文的发表时间）