Physical Oligomer/Polymer Gels: Self-Sorting and Stimuli-Responsive Gelation Properties
Polymer self-sorting1-the ability of polymers to recognize itself or other polymers, and discriminate the rest in a complex molecular mixture is commonly observed in biological systems such as DNA recognition.On the other hand, polymer gels that can show stimuli-responsive properties is also a topic of practical interest.2-4 Based on our recent studies of click oligomers/polymers,5-9 we will present our recent findings on the synthesis of several click oligomers/polymers 1-3 that exhibit both properties described above.Examples will also be given to show how the degree of oligo-/polymerization,side-chain substitution, monomer dipole orientation and backbone rigidity on their self-association properties which are manifested in their differential gelation power, anion-and photo-responsive, and self-sorting capabilities.
H.-F.Chow H.-Z.Wang K.Zheng
Department of Chemistry, Center of Novel Functional Molecules, and Institute of Molecular Functional Materials, The Chinese University of Hong Kong
国际会议
9th International Symposium on High-Tech Polymer Materials(第9届国际高技术高分子材料学术会议)(HTPM-9)
郑州
英文
16-16
2016-07-11（万方平台首次上网日期，不代表论文的发表时间）