Unusual formation of Bis(5,6,7-trihydroquinolyl)-fused benzodiazepines and their Mg & Al complexes for ε-caprolactone polymerization

摘要：

Polycaprolactone and poly(lactide) are two very important polymers used in agricultural,biomedical and environmental fields due to their tuneable properties and biodegradability.1 Since discrete metal complexes produced polymers contains the residual trace of catalyst, magnesium and aluminum remains a promising catalyst due to its lack of toxicity and essential for human life.Recently, significant amount of bimetallic / trimetallic complexes stabilized by tetradentate ligands were reported towards the ROP of cyclic esters due to probably bimetallic active species facilitate the cooperation between two metal centers in polymerization reactions, which are considered for improving their activities.

作者: Natesan Mannangatti Raiendran Wenjuan Zhang Wen-Hua Sun

作者单位: Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing

会议类型: 国际会议

会议名称: 9th International Symposium on High-Tech Polymer Materials(第9届国际高技术高分子材料学术会议)(HTPM-9)

会议地点: 郑州

会议语种:英文

页码: 31-31

在线出版日期: 2016-07-11（万方平台首次上网日期，不代表论文的发表时间）