Design and Synthesis of (Imido)vanadium-Alkylidene Complex Catalysts for Ring-Opening Metathesis Polymerization of Cyclic Olefins

摘要：

Since classical Ziegler type vanadium catalyst systems demonstrate unique characteristics (notable reactivity toward olefins), design of the vanadium complex catalysts, especially chemistry of the alkylidene complexes thus attracts considerable attention in terms not only of better catalyst design, but also of better understanding in organometallic chemistry.1 We herein present a series of (arylimido)vanadium(Ⅴ)-alkylidene complexes which are effective for ring-opening metathesis polymerization (ROMP) of norbornene (NBE) and the derivatives.

作者: Xiaohua Hou Kotohiro Nomura

作者单位: Department of Chemistry, Tokyo Metropolitan University, Tokyo 192-0397, Japan

会议类型: 国际会议

会议名称: 9th International Symposium on High-Tech Polymer Materials(第9届国际高技术高分子材料学术会议)(HTPM-9)

会议地点: 郑州

会议语种:英文

页码: 61-62

在线出版日期: 2016-07-11（万方平台首次上网日期，不代表论文的发表时间）