A NOVEL HIGH CHARRING POLYMER BASED ON FERROCENE: SYNTHESIS, CHARACTERIZATION AND THERMAL PROPERTY

摘要：

　　A novel high charring polymer based on ferrocene (PDCFEN) has been successfully synthesized by Aza-Michael addition method.The intermediates 1,1-diacetylferrocene(DAF) was synthesized by Fridel-Crafts and 1,1-dicinnamoylferrocene(DCF) was prepared by Claisen-Schmidt condensations with ultrasound technology, respectively.The synthetic conditions of three products have been optimized.All products were characterized through FT-IR, 1H NMR,13C NMR, LC-MS and GPC.In addition, the thermal degradation property of PDCFEN was investigated by TGA.The TGA result shows that four main weight loss stages can be distinguished.The third stage is obvious different with other ferrocene-based polymer and 62.85% char residue is obtained at 800 ℃.

作者: DuiJun Liao QiKui Xu QuanTong Zhang XiaoPing Hu

作者单位: School of Material Science and Engineering,Southwest University of Science and Technology, Mianyang 621010, P.R.China

会议类型: 国际会议

会议名称: 4th International Symposium on Flame-Retardant Materials & Technologies(ISFRMT 2016)(第四届阻燃材料与技术国际研讨会 )

会议地点: 长春

会议语种:英文

页码: 181-182

在线出版日期: 2016-06-15（万方平台首次上网日期，不代表论文的发表时间）