SYNTHESIS AND APPLICATIONS OF SOYBEAN-OIL-BASED PHOSPHORUS-CONTAINING POLYOLS ON RIGID POLYURETHANE FOAMS

摘要：

　　In this paper, epoxidized soybean oil (ESO) was used as a raw material to react with 2-carboxyethyl (phenyl) phosphinic acid (CEPPA) to obtain phosphorus-containing soybean-oil-based polyols (PCSO).Then, the structure of PCSO was characterized by determination of epoxide and hydroxyl equivalent, as well as analysis of FTIR and 31p NMR spectra.Finally, PCSO was used to prepare inherently flame-retardant rigid polyurethane foams (RPUF).The flame retardancy of foams was evaluated by LOI and UL-94.The tested results showed that the LOI value of RPUF-PCSO was increased by 1.5% compared with neat RPUF, and its UL 94 test level was improved from NR to V-1.After combining with commercial phosphorus-containing polyols (BY30), its LOI value and UL 94 classification were further improved to 22.5% and V-0,respectively.

作者: X.Wang X.L.Li M.J.Chen Z.G.Liu L.Zhong J.Q.Liu Q.T.Huang

作者单位: School of Science (Sichuan), Xihua University, Chengdu 610039, China

会议类型: 国际会议

会议名称: 4th International Symposium on Flame-Retardant Materials & Technologies(ISFRMT 2016)(第四届阻燃材料与技术国际研讨会 )

会议地点: 长春

会议语种:英文

页码: 195-196

在线出版日期: 2016-06-15（万方平台首次上网日期，不代表论文的发表时间）