THERMAL DEGRADATION AND COMBUSTION BEHAVIORS OF EPOXY RESINS WITH PHOSPHORUS-SILICON OR PHOSPHORUS-NITROGEN SYNERGISTIC FLAME RETARDANTS

摘要：

　　A novel phosphorus-nitrogen synergic flame retardant, 1,3,5-tris(3-(diphenylphosphoryl)propyl)-l,3,5-triazinane-2,4,6-trione (FR-1), and another analogous phosphorus-silicon synergic flame retardant (1,1,3,3-tetramethyl-1,3-disiloxanediyl)-di-2,1-ethanediyl-bis(diphenylphosphine oxide) (FR-2) were synthesized and used in the flame retardancy of o-cresol novolac epoxy/phenolic novolac hardener system.Experimental results revealed that FR-1 showed superior flame retardant efficiency to that of FR-2.With the same flame retardant content, the residue char of epoxy thermosets with FR-2 was higher than that of epoxy thermosets with FR-1 at 750 ℃.X-ray photoelectron spectroscopy data revealed that phosphorus exhibited different combustion behaviors when combined with nitrogen or silicon.

作者: Zhi-sheng Li Tao Song Jin-gang Liu Yue Yan

作者单位: Beijing Institute of Aeronautical Materials, Beijing 100095, China Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

会议类型: 国际会议

会议名称: 4th International Symposium on Flame-Retardant Materials & Technologies(ISFRMT 2016)(第四届阻燃材料与技术国际研讨会 )

会议地点: 长春

会议语种:英文

页码: 246-247

在线出版日期: 2016-06-15（万方平台首次上网日期，不代表论文的发表时间）