Ring-Opening Metathesis Polymerization of Cyclic Olefins by (Imido)vanadium-Alkylidene Complexes

摘要：

Design and synthesis of vanadium complex catalysts for olefin polymerization attract considerable attention due to the unique characteristics (notable reactivity toward olefins) observed in the classical Ziegler type catalysts.1 We focus on synthesis and reaction chemistry of high oxidation state (imido)vanadium(Ⅴ)-alkyl,alkylidene complexes, and demonstrated that these alkylidene complexes are highly effective for ring-opening metathesis polymerization (ROMP) of norbornene (NBE) and the derivatives.1-3 In particular, the fluorinated aryloxo analogue (1) showed the higher activity.

作者: Xiaohua Hou Akiko Inagaki Kotohiro Nomura

作者单位: Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami Osawa, Hachioji,Tokyo 192-0397, Japan

会议类型: 国际会议

会议名称: 8th International Symposium on High-Tech Polymer Materials(第8届国际高技术高分子材料学术会议)

会议地点: 北京

会议语种:英文

页码: 98-99

在线出版日期: 2014-07-01（万方平台首次上网日期，不代表论文的发表时间）