Isoprene Polymerization Using Neodymium 8-Quinolinolates in Presence of Alkylaluminums

摘要：

Neodymium (Nd) based catalytic systems have attracted great attention for the polymerization of isoprene in both academia and industry due to their high catalytic activity and high cis-1, 4 selectivity.1 Some Nd 8-quinolinolate complexes were synthesized in reasonable isolated yields and have been fully characterized in this paper.1,2 The binary catalyst system neodymium 8-quinolinolate complexes and TIBA showed high polymerization activities.All the compounds can be carried out under an air atmosphere without Schlenk techniques.The highest activity is up to 105 g·mol-1 (Nd) ·h-1 for the polymerization of isoprene.

作者: Zhonghua Wang Yongqiang Qian Wen-Hua Sun

作者单位: Key laboratory of Engineering Plastics, Institute of Chemistry,Chinese Academy of Sciences, Beijing 100190, China

会议类型: 国际会议

会议名称: 8th International Symposium on High-Tech Polymer Materials(第8届国际高技术高分子材料学术会议)

会议地点: 北京

会议语种:英文

页码: 156-156

在线出版日期: 2014-07-01（万方平台首次上网日期，不代表论文的发表时间）