To Explore High Magnetoelectrochemical Chirality
Cu films were electrodeposited under a magnetic field of 5 T on the Pt disc electrodes with diameters of 3 mm~25 μm.Such magnetoelectrodeposited(MED)Cu films were employed as an electrode,and cyclic voltammograms were measured for the electrochemical reactions of an amino acid of alanine.Chiral behavior was observed as oxidation current difference between the enantiomers.Clear magnetoelectrochemical chirality was observed on the micro-disk electrode and on the kinetic-controlled electrode process of alanine.The chiral response was durable for more than 10 cycles of the consecutive voltammetric measurements of the enantiomers.
magnetoelectrodeposition chirality MHD effect micro-electrode copper
MOGI Iwao AOGAKI Ryoichi MORIMOTO Ryoichi WATANABE Kazuo
IMR,Tohoku University,Katahira,Sendai 980-8577,Japan Polytechnic University,Sagamihara,Kanagawa 252-5196,Japan Saitama Prefectural Okubo Water Filtration Plant,Saitama 338-0814,Japan
国际会议
The 7th International Conference on Electromagnetic Processing of Materials(第七届冶金与材料电磁过程国际大会)
北京
英文
1-4
2012-10-22(万方平台首次上网日期,不代表论文的发表时间)