Hydrogen evolution on binary and ternary cobalt alloys deposited with superimposed magnetic field

摘要：

　　The article presents results of electrodeposition of Co-Mo Co-Mo-C alloys in a magnetic field characterized by low overvoltage of hydrogen evolution.Addition of molybdenum and carbon was to lower the values of overvoltage of hydrogen evolution on cobalt.The influence of bath pH,bath composite,current density and magnetic field with different orientation on the deposits composition,structure and overpotential for hydrogen evolution reaction(HER)was determined.Electrocatalytic properties of the obtained alloy coatings within the range of hydrogen evolution were tested in a concentrated NaOH solution.The comparison of electrocatalytic properties of Co-Mo alloys with properties of Co-Mo-C ones enabled determining the influence of carbon presence in cathodic deposits on the overpotential values for hydrogen evolution.

关键词： Co-Mo alloys Co-Mo-C alloys hydrogen evolution magneto-electrochemistry

作者: ZABINSKI Piotr MECH Krzysztof KOWALIK Remigiusz

作者单位: Faculty of Non-Ferrous Metals,AGH University of Science and Technology,Cracow,Poland

会议类型: 国际会议

会议名称: The 7th International Conference on Electromagnetic Processing of Materials(第七届冶金与材料电磁过程国际大会)

会议地点: 北京

会议语种:英文

页码: 1-5

在线出版日期: 2012-10-22（万方平台首次上网日期，不代表论文的发表时间）