Some nitrotriazole-substituted high explosives

摘要：

　　5-amino-3-notro-l,2,4-triazole (ANTA) and 4-amino-5-nitro-l,2,3-triazole (ANTZ) are both insensitive explosives.Because of nitrogen atom contained triazole ring with rich-electrons for ANTA and ANTZ, they are regared as nucleophilic reagents, and can react with some of chloro-substituted nitroaromatics to yield ANTA-and ANTZ-substituted energetic materials (explosives), such as 2-(5-amino-3-nitro-1,2,4-triazol-l-yl)-3,5-dinitropyridine (PRAN), 2-(4-amino-5-nitro-l,2,3-triazol-2-yl)-3,5-dinitropyridine (LLM133), and so on.In an analogous manner, other nitrotrizoles including 3,5-dinitro-l,2,4-triazole (DNTA), 4,5-dinitro-l,2,3-triazole (DNTZ) and their mononitrotriazoles can also react with some of chloro-substituted nitroaromatics to yield nitrotriazole-substituted explosives.These nitrotriazole-substituted explosives are reviewed in this papers.

关键词： organic chemistry nitrotriazole 5-amino-3-notro-1,2,4-triazole (ANTA) 4-amino-5-nitro-1,2,3-triazole (ANTZ) insensitive explosives

作者: ZHANG Guangquan HUANG Ming

作者单位: Institute of Chemical Mterials,CA EP,Mianyang 621900,China

会议类型: 国际会议

会议名称: 2013 International Autumn Seminar on Propellants, Explosives and Pyrotechnics(2013国际推进剂、炸药、烟火技术秋季研讨会)

会议地点: 成都

会议语种:英文

页码: 17-23

在线出版日期: 2013-09-24（万方平台首次上网日期，不代表论文的发表时间）