Ultrasonic Assisted Dynamic Inverse Emulsion:A Novel Polymerization Technique to Prepare Conductive Polyaniline/Palygorskite Composite
(0) The present work describes an ultrasonic assisted in-situ dynamic inverse emulsion polymerization process of aniline (ANI) in the presence of organic palygorskite (OPGS) in toluene.Core-shell structure of electrically conducting polymerized ANI (PANI) combined with OPGS was prepared by utilizing the method.Dodecylbenzenesulfonic acid (DBSA) was used as the dopant and emulsifier.The OPGS was obtained via the chemical reaction of pretreated palygorskite with hexadecyltrimethyl ammonium bromide (HTAB).The prepared PANI/OPGS composite was characterized by FT-IR, UV-Vis, XRD, TGA and SEM.In addition, the conductivity was evaluated at different ANI/OPGS weight ratio.When the ANI/OPGS weight ratio increased to 2∶7, the conductivity of the composite still remained at 10 S/m at room temperature.The results demonstrated that ultrasonic assisted dynamic inverse emulsion would be an excellent polymerization technique to increase the conductivity and the polymerization rate.
Polyaniline Polygorskite Conductivity Core-shell structure
Zhe Zhang Xiao-liang Wang Jian Xu Heng-chang Ma Zi-qiang Lei
The Ministry of Education Key Laboratory of Eco-Environment-Related Polymer Materials, Gansu 730070, China; The Gansu Province Key Laboratory Polymer Materials, Gansu 730070, China; College of Chemistry and Chemical Engineering of Northwest Normal University, Gansu 730070, China
国际会议
The Eighth China National Conference on Functional Materials and Applications(第八届中国功能材料及其应用学术会议)
哈尔滨
英文
507-513
2013-08-23（万方平台首次上网日期，不代表论文的发表时间）