A Green Procedure for the Ionic Liquid Catalyzed Oxidation of Benzylic Alcohols to Aldehydes or Ketones in Aqueous Media

摘要：

　　A green oxidation of benzylic alcohols to the corresponding aldehydes or ketones was achieved in aqueous media using ionic liquid/H2O2/HCl catalytic oxidation system.The procedure is mild, environment-friendly and simple.Ionic liquids can be successfully recovered and reused for the oxidation of the same (different) substance.The directing effect of the ionic liquid is supported by the good selectivities and yields.These reactions demonstrate the catalytic oxidation and phase transfer function of the ionic liquid is stronger than that without ionic liquid.

关键词： Ionic liquids Alcohols Oxidation Aldehydes Ketones

作者: Guo-feng Zhang Lu-yang Chen Chao Liu Xiu-iie Ji Bo-wen Cheng Jun Song Fei Lu Ran-ran Fu Jie-ru Huang Peng-he Su Xiao-rong Gou

作者单位: State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Tianjin Polytechnic Universit School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, P.R.Chi

会议类型: 国际会议

会议名称: The Eighth China National Conference on Functional Materials and Applications(第八届中国功能材料及其应用学术会议)

会议地点: 哈尔滨

会议语种:英文

页码: 567-570

在线出版日期: 2013-08-23（万方平台首次上网日期，不代表论文的发表时间）