Structure Studies on Order Assemblage of ManganeseⅡ Complexes

摘要：

　　The manganeseⅡ complex Mn(C9H9O3)2(H2O)2,the MnⅡ atom is located on a twofold axis and is coordinated by two ethylvanillinate anions and two water molecule in a distorted octahedral geometry.The ethylvanillinate ligand chelates to the MnⅡ atom through its ethyl and hydroxyl O atoms,with greatly differing Mn-O bond distances (2.3988(15)(A) and 2.0675(13)(A)).Adjacent complex link to each other via hydrogen bonds forming the three-dimensional supramolecular structure.

关键词： manganeseⅡ complex photosystem Ⅱ electrostatic interaction supramolecular structure

作者: Yu Liu Shanshan Zhang Jian Gao Tianzhu Yang Hongxiao Tian

作者单位: Department of Chemistry,Shandong Polytechnic University,Jinan,P.R.China Department of Chemistry,Shandong Polytechnic University,Jinan,P.R.China;Weifang University of Scienc Chemical Technology Academy of Shandong Province,Jinan,P.R.China

会议类型: 国际会议

会议名称: 2013 International Conference on Advanced Engineering Materials and Architecture Sciences(2013先进工程材料与建筑科学国际会议)(ICAEMAS 2013)

会议地点: 西安

会议语种:英文

页码: 122-125

在线出版日期: 2013-07-27（万方平台首次上网日期，不代表论文的发表时间）