Synthesis and self-assemble behavior of Block copolymerization of Vinyl acetate and N-Vinylacetamide

摘要：

　　Polymerizations of VAc was carried out using AIBN as the initiator and DIP as the MADIX agent precursor.Then,block copolymer PVAc-b-PNVA had been synthesized by RAFT radical polymerization in the presence of PVAc-DIP as macro CTA.The length of blocks could be tuned by changing the molar ratio of NVA and VAc.Block copolymer PVAc-b-PNVA self-assembled into micelles in solution,and underwent microphase separation in bulk state.

关键词： N-vinylacetamide (NVA) Vinyl acetate Block copolymer self-assembly

作者: LOU Yu SHI Dongjian DONG Weifu CHEN Mingqing

作者单位: The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China

会议类型: 国际会议

会议名称: 2013 International Conference on Intelligent System,Applied Materials and Control Technology(GSAMCT2013)(2013年智能系统、应用材料和控制技术国际会议)

会议地点: 太原

会议语种:英文

页码: 10-14

在线出版日期: 2013-01-13（万方平台首次上网日期，不代表论文的发表时间）