Synthesis of PMMA by Single-Electron Transfer Radical Polymerization Using Benzyl Chloride as Initiator

摘要：

　　Single electron transfer living radical polymerization (SET-LRP) has developed to be a robust tool for the construction of well-designed polymers.This paper reports the influence of one cheaper initiator on the SET-LRP process.The SET-LRP of methyl methacrylate (MMA) initiated with benzyl chloride and catalyzed by Cu(0)/PMDETA at 25℃ in methanol is described.The polymerization kinetics was recorded.The reactions followed first-order kinetic in monomer consumption and the molecular weights increased linearly with conversion while retaining narrow molecular weight distribution.Therefore,it is plausible that SET-LRP of MMA initiated with benzyl chloride process to yield well defined macromolecules.

关键词： benzyl chloride methyl methacrylate single electron transfer living radical polymerization (SET-LRP)

作者: Changqing Fu Xiaobo Wei Liang Shen

作者单位: Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University,Nanchang 330013,P.R.China

会议类型: 国际会议

会议名称: 2013 International Conference on Intelligent System,Applied Materials and Control Technology(GSAMCT2013)(2013年智能系统、应用材料和控制技术国际会议)

会议地点: 太原

会议语种:英文

页码: 85-88

在线出版日期: 2013-01-13（万方平台首次上网日期，不代表论文的发表时间）