Adsorption Kinetics and Thermodynamics of Methyl Orange on Ethylenediamine-Modified Chitosan Magnetic Nano-Adsorbent
Ethylenediamine-modified chitosan magnetic nano-adsorbent (EMCN) was prepared and used for the sorption of methyl orange(MO).The kinetics of the sorption fitted well with the pseudo-second-order kinetics model.The activation energy of sorption (Ea) was determined to be 16.47 kJ.mol-1.Adsorption isotherms showed that the sorption process was consistent with both Langrnuir and Freundlich isotherm,and the thermodynamic parameters were calculated and indicated that the sorption process was spontaneous and exothermic.The saturated sorption capacity is 247.66,227.58,214.19 mg.g-1 at 5℃,25℃,45℃ (pH=5.6),respectively.
Chitosan Magnetic nano-adsorbent Thermodynamics Kinetics
Yu Hong CHEN Si Qian HU
School of Chemistry and Environmental Engineering, Jianghan University, Wuhan 430056, P.R.China
国际会议
昆明
英文
273-276
2012-10-12(万方平台首次上网日期,不代表论文的发表时间)