会议专题

On the Solubility of Chromium in the Cubic Carbide and M7C3 Carbide in the WC-Co-Cr-Ti and WC-Co-Cr-Nb Systems

  The solubility of Cr in cubic carbides in the systems WC-Co-TiC and WC-Co-NbC has been determined using equilibrium samples.Thermodynamic calculations were used to design the alloys through extrapolations of Gibbs energy expressions.The alloys were designed to have a microstructure containing the following phases:WC,liquid,M7C3,graphite and cubic carbide.The alloys were investigated using scanning electron microscopy and analyzed using energy-dispersive X-ray spectrometry.The present work shows how the Cr solubility depends on which cubic carbide former that is present.The WC-Co-Cr-Zr alloy has no detectable amount of Cr whereas the WC-Co-Cr-Ti alloy has 17% Cr in the cubic carbide.

Cr cubic carbides thermodynamics SEM EDS

Susanne Norgren Alexandra Kusoffsky

Sandvik Mining,R&D Rock Tools,Stockholm,Sweden;Department of Materials Science,The(A)ngstr(o)m Labor Sandvik Hard Materials,R&D Hard Materials,Coventry,UK

国际会议

2012 Zhuzhou International Conference on Cemented Carbides(株洲硬质合金国际学术会议)

株洲

英文

201-205

2012-09-12(万方平台首次上网日期,不代表论文的发表时间)