Synthesis of sludge@carbon nanocomposite for the recovery of As (V) from wastewater
A novel type of sludge@carbon nanocomposite was synthesized using municipal sewage sludge as raw material and ferrous iron sulphate as catalyst through hydrothermal carbonization (HTC) process.The prepared adsorbent was characterized by various analytical techniques as Scanning electron microscopy (SEM),transmission electron microscope (TEM) and X-ray diffraction patterns (XRD).The adsorption capacity of this nanocomposite for As(V) has been studied using a batch method.Various parameters affecting sorption such as pH,contact time and sorbate concentration were investigated and optimal experimental conditions were determined.It was found that 0.5 h was sufficient for complete removal of 0.5 mg/l As(V) from polluted water.The suitable adsorbent dosage and pH value were 3.6 g/l and 5.0,respectively.The arsenic desorbed could subsequently be separated by 0.5M NaOH solution.A modified linear driving force model conjugated with Langmuir isotherm was created to describe the adsorption kinetics.The resultant modified sewage sludge demonstrated a substantially high adsorption capacity of As(V) in comparison with dried sewage sludge and many other adsorbents reported in literature.The rates of adsorption were found to conform to the pseudo-second order kinetic model.The intm-particle diffusion was identified to be the rate-limiting step.The sludge@carbon nanocomposite could be reused after two adsorption-desorption cycles.
Nanocomposite sewage sludge adsorption arsenic removal
S.E.A.Sharaf El-Deen Fushen Zhang
Department of Environmental Nano-materials, Research Center for Eco-Environmental Sciences, Chinese Department of Environmental Nano-materials, Research Center for Eco-Environmental Sciences, Chinese
国际会议
The Seventh International Conference on Waste Management and Technology(第七届固体废物管理与技术国际会议(ICWMT7))
北京
英文
378-390
2012-09-05（万方平台首次上网日期，不代表论文的发表时间）