Effect of Functionalization of Multi-walled Carbon Nanotubes with 4-Allyloxy-biphenyl-4-ol on Electrical Conductivity and Mechanical Properties of Silicon Resin Nanocomposites

摘要：

　　In order to improve electrical conductivity of electronic packaging materials,we synthesize 4’-allyloxy-biphenyl-4-ol (AOBPO) and use the AOBPO functionalized MWCNTs(AMWCNTs) as fillers mixed with silicone resin to fabricate nanocomposites.The electrical and mechanical performances of the nanocomposites were investigated by using dynamic mechanical analysis (DMA) and integrated electrochemical analyzer.The results show that AOBPO can disperse carbon nanotubes via π–π interactions and has good compatibility with the silicone resin matrix.the A-MWCNTs/silicon resin nanocomposites has a higher electrical conductivity than the unfunctionalized MWCNTs(U-MWCNTs)/silicon resin nanocomposites,and A-MWCNTs/silicone resin nanocomposites has a lower storage modulus than the UMWCNTs/ silicon resin nanocomposites,These results prove the effect of functionalization of MWCNTs with AOBPO on the interfacial adhesion and dispersion between silicon resin and MWCNTs,Which is further confirmed by morphology study of fractured surfaces of nanocomposites by SEM.

关键词： electrical conductivity MWCNTs nanocomposites electronic packaging

作者: Xue Gao Dayong Gui Wentao Zeng Weiling Chen Jianhong Liu

作者单位: School of Chemistry and Chemical Engineering,Shenzhen University,Nanhai Ave 3688,Shenzhen,Guangdong 518060,P.R.China

会议类型: 国际会议

会议名称: 2012 International Conference on Electronic Packaging Technology & Hiigh Pachaging(2012电子封装和高密度封装国际会议(ICEPT-HDP2012))

会议地点: 桂林

会议语种:英文

页码: 227-231

在线出版日期: 2012-08-13（万方平台首次上网日期，不代表论文的发表时间）