Synthesis and Properties of Cellulose Diacetate graft Poly(p-dioxanone) Copolymers Via the Couple-Grafting Copolymerization
A new biodegradable copolymer of cellulose diacetate and poly(p-dioxanone) (PPDO) was prepared through a couple-grafting procedure.PPDO was functionalized with the isocyanate group,and then PPDO terminated with the isocyanate group was enabled to react with the hydroxyl groups of cellulose diacetate.The length of PPDO graft chains can be controlled easily by using the prepolymers of PPDO with different molecular weights.The resulting products were thoroughly characterized with FT-IR,1H-NMR.The mechanical properties of the copolymers were affected greatly by the length of PPDO segment.
Cellulose diacetate P-dioxanone Graft copolymer Mechanical property
Jiang Zhu XiuLi Wang
ChongQing University of Arts and Sciences, ChongQing 402160, P.R.China Center for Degradable and Flame-Retardant Polymeric Materials; Key Laboratory of Green Chemistry and
国际会议
太原
英文
3-7
2012-06-23(万方平台首次上网日期,不代表论文的发表时间)