Effects of Diameters on the Catalytic Activity of Spherical V-MCM-41 in the Selective Oxidation of Styrene
Spherical V-MCM-41s with different diameter are synthesized by direct hydrothermal method through the precise control over the molar ratio of NaOH/TEOS.Vanadium supported on spherical MCM-41s is also prepared by impregnation methods.They are used as heterogeneous catalysts for the oxidation of styrene with H2O2 as oxidant.The results suggest that all catalysts have high catalytic activity,which increases with their diameter decreasing.
MCM-41 Nanosphere Vanadium Styrene oxidation
Yu Chen Hua Qin Xiaobo Shi Yan Kong
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
国际会议
太原
英文
137-140
2012-06-23(万方平台首次上网日期,不代表论文的发表时间)