Study of effect of water on the physicochemical properties of 1-buthyl-3-methylimidazolium Chloride ionic liquids

摘要：

　　The density,viscosity,conductivity and the electrochemical window of 1-buthyl-3-methyl-imidazolium Chloride ionic liquids(BmimCl) and its water mixture have been determined at 298.15 K and atmospheric pressure.It was found that the density and conductivity of BmimCl/water,increase with the increase the water concentration at the same temperature,whereas the viscosity and electrochemical windows of BmimCl/water decrease.The viscosity of pure ionic liquids decreases with the increase of the temperature,whereas the conductivity increases.The relationship between the conductivity and the temperature agrees well with the Arrhenius equation k =k∞exp-Ea/kBTand the active energy of conduction is determined accordingly.

关键词： Ionic liquids 1-buthyl-3-methyl-imidazolium Chloride water Physical and chemical properties

作者: Guocai Tian Hankun Feng Jinliang Zhang

作者单位: Faculty of Metallurgicaland Energy Engineering, Kunming University of Science and Technology,650093, Kunming, Yunnan, China

会议类型: 国际会议

会议名称: 2012 2nd International Symposium on Chemical Engineering and Material Properties(ISCEMP2012)(2012第二届化学工程与材料特性国际研讨会)

会议地点: 太原

会议语种:英文

页码: 152-156

在线出版日期: 2012-06-23（万方平台首次上网日期，不代表论文的发表时间）