Structure, Acid Properties and Catalysis Performance of MCM-22 Family Zeolites on the Alkylation of Benzene with Propylene
MCM-22 family zeolites (MCM-22,MCM-49 and MCM-56) have been synthesized hydrothermally by dynamic method.All materials were characterized by different techniques,such as XRD,N2 adsorption-desorption and NH3-TPD.The catalyst performance of MCM-22 family zeolites have been studied on the alkylation of benzene with propylene in liquid phase.Result shows that MCM-22 family zeolites are excellent alkylation catalysts for the produce of cumene.Compared to MCM-22 and MCM-49,MCM-56 shows higher catalytic activity in a relatively low reaction temperature and higher monoalkylation selectivity in a relatively low benzene-to-propylene ratio.
MCM-22 family zeolite Alkylation Cumene
Fei Zhao Yu Zhang Shudong Geng Lianfa Chen Wei Wang
Dept.of Materials Engineering, Jilin Institute of Chemical Technology, Jilin City 132022 China
国际会议
太原
英文
283-286
2012-06-23(万方平台首次上网日期,不代表论文的发表时间)