Effect of hydrogen peroxide detemplation on the structure and acid properties of MCM-56 zeolite
MCM-56 zeolite has been synthesized by dynamic hydrothermal method.The template of as-made MCM-56 was removed by two methods.One is traditional calcination,the other is hydrogen peroxide post-treatment.All materials were characterized by different techniques,such as XRD,N2 adsorption-desorption,NH3-TPD and FTIR.Results show that the template of as-made MCM-56 could be removed effectively by hydrogen peroxide post-treatment.The topology of the hydrogen peroxide treated MCM-56 remains unchanged.The BET surface area and external surface area of MCM-56 zeolite could be obviously improved by hydrogen peroxide treatment.The amount of acid sites was increased by hydrogen peroxide treatment but the acid strength was not modified.
MCM-56 zeolite hydrogen peroxide detemplation
Fei Zhao Yu Zhang Haijun Xing Mingjun Jia Tonghao Wu
Dept.of Materials Engineering, Jilin Institute of Chemical Technology, Jilin City 132022 China College of Chemistry, Jilin University, Changchun City 130023 China
国际会议
太原
英文
396-400
2012-06-23(万方平台首次上网日期,不代表论文的发表时间)