Chemical fixation of carbon dioxide catalyzed by bimetallic aluminum(salen) complex

摘要：

　　Bimetallic aluminum(salen) complexes were prepared and used as catalyst for the synthesis of DPC from CO2 and phenol in the presence of carbon tetrachloride.The bimetallic complex derived from 3,5-ditert salicylaldehyde and 1,2-cyclohexanediamine revealed more excellent activity than that obtained in the presence of other complexes and the simple Lewis acid ZnCl2.The influence of the amount of complex and the reaction conditions including the pressure of CO2 and the reaction temperature was also investigated.

关键词： Bimetallic aluminum(salen) complex carbon dioxide phenol diphenyl carbonate

作者: Zhenxiao Duan Tao Fang Min Wang Guozhi Fan

作者单位: School of Chemicaland EnvironmentalEngineering, Wuhan Polytechnic University, Wuhan,430023, China

会议类型: 国际会议

会议名称: 2012 2nd International Symposium on Chemical Engineering and Material Properties(ISCEMP2012)(2012第二届化学工程与材料特性国际研讨会)

会议地点: 太原

会议语种:英文

页码: 406-410

在线出版日期: 2012-06-23（万方平台首次上网日期，不代表论文的发表时间）