Experimental Study on Catalytic Oxidation of Cyclohexane Catalyzed by Phosphomolybdic Acid

摘要：

　　The catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol using hydrogen peroxide over phosphomolybdic acid were studied.Factors such as the amount of catalyst,amount of the oxidant (H2O2),reaction temperature and reaction time were investigated.The conversion of cyclohexane was 35.35%,the total selectivity to cyclohexanone and cyclohexanol was 97.68% at a reaction temperature of 70 ℃,reaction time of 8 h,10 mL of acetone,0.01 g of phosphomolybdic acid and 0.5 mL of hydrogen peroxide.

关键词： phosphomolybdic acid cyclohexane catalytic oxidation hydrogen peroxide

作者: Jiaojing Zhang Hualin Song Jian Wang Hua Song

作者单位: Chem.& Chem.Eng.College, Northeast Petroleum University, 199 Fazhan Rd., High-Tech Zone,Daqing 16331 Department of Image College, Mudanjiang Medical University,No.3 Tongxiang Street, Aimin District, Mu

会议类型: 国际会议

会议名称: 2012 2nd International Symposium on Chemical Engineering and Material Properties(ISCEMP2012)(2012第二届化学工程与材料特性国际研讨会)

会议地点: 太原

会议语种:英文

页码: 411-414

在线出版日期: 2012-06-23（万方平台首次上网日期，不代表论文的发表时间）