Low Potential Electrochemical Polymerization of 1-Hydroxy-2-methoxybenzene and Characterization of Its Polymer

摘要：

　　The electrochemical polymerization of 1-hydroxy-2-methoxybenzene (HMOB) was performed in boron trifuoride diethyl etherate (BFEE) and a novel conducting polymer poly(1-hydroxy-2-methoxybenzene) (PHMOB) was easily electrodeposited.The oxidation onset of HMOB was initiated at 0.97 V versus a saturated calomel electrode (SCE).PHMOB films obtained from BFEE showed good thermal stability.NMR studies showed that the polymerization of HMOB occurred at C4 and C5 position.Fluorescent spectral studies indicated that doped and dedoped PHMOB were good blue emitters,with the same excitation wavelength maximum of 348 nm.

关键词： PEDOT derivatives Poly(1-hydroxy-2-methoxybenzene) Conducting Polymers Electrochemical Polymerization Fluorescence Property

作者: Yao Huang Mulin Ma Houting Liu Jingkun Xu Ge Zhang Leiqiang Qin

作者单位: Jiangxi Key Laboratory of Organic Chemistry,Jiangxi Science and Technology Normal University,Nanchang 330013,China

会议类型: 国际会议

会议名称: 2012 International Conference on Intelligent System and Applied Material(2012智能系统与应用材料国际会议)(GSAM2012)

会议地点: 太原

会议语种:英文

页码: 170-175

在线出版日期: 2012-01-13（万方平台首次上网日期，不代表论文的发表时间）