New Polymeric Membrane Sensor Doped with N,N-bis(benzoin)-1,2-phenylenediamine for Selective Determination of Aluminum

摘要：

　　A new polymenc membrane sensor for A13+ based on bis(benzoin)-1,2-phenylenediamine as a neutral carrier was investigated.The proposed sensor exhibits a near-Nernstian response for A13+ over a wide linear range of 3.Ox10-7 to 1.Oxl0-1 mol/L,with a detection limit of 1.Ox10-7 mol/L and a slope of 19.7±0.3 mV/decade.The sensor displays a good selectivity toward A13+ over other cations in pH range of 2.5 t0 4.0.It has relatively fast response time (8 s) and can be used at least for 3 months without considerable divergence in potential.The response mechanism was discussed in view of the A.C.impedance technique.It was successfully used as an indicator electrode in the determination of aluminum m real samples.

关键词： Bis(benzoin)-1 2-phenylenediamine PVC membrane Al3+ sensor

作者: Xinlu Liu Bin Xie Xunhai Pan Kangquan Qiao Ying Wang

作者单位: College of Chemistry and Pharmaceutical,Sichuan University of Science and Engineering 643000,Zigong, Institute of Functional Material,Sichuan University of Science and Engineering,Zigong 643000,China College of bioengineering,Sichuan University of Science and Engineering,Zigong 643000,China

会议类型: 国际会议

会议名称: 2012 International Conference on Intelligent System and Applied Material(2012智能系统与应用材料国际会议)(GSAM2012)

会议地点: 太原

会议语种:英文

页码: 336-341

在线出版日期: 2012-01-13（万方平台首次上网日期，不代表论文的发表时间）