Kinetic parameters evaluation for isoprene mixed with aluminum oxide

摘要：

　　We analyzed the basic hazard characteristics for isoprene in the manufacturing process by evaluating the runaway reaction,kinetic parameters and safety parameters in this study.Experiments were carried out by calculating the thermal decomposition reactions for isoprene and mixed with aluminum oxide in non-isothermal conditions by differential scanning calorimetry (DSC).Afterwards results indicated that isoprene had a conjugated double bond of unstable structure,and therefore it was prone to produce exothermic reaction during the process of polymerization.Aluminum oxide was applied to mix with isoprene,which could increase the heat release rate.Based on the results,safety information should be provided to government and relevant industries for prevention the accident occur in relevant plants.

关键词： isoprene runaway reaction kinetic parameters aluminum oxide differential scanning calorimetry (DSC)

作者: J.Z.LIN J.L.CHEN Y.F.LIN C.M.CHANG W.D.YANG C.P.LIN J.M.TSENG C.S.KAO

作者单位: Institute of Safety and Disaster Prevention Technology,Central Taiwan University of Science and Tech Department of Chemical and Materials Engineering,National Kaohsiung University of Applied Sciences,K Department of Chemistry,National Chung Hsing University,250 Kuo-Kwang Rd.,Taichung,Taiwan,China Division of Occupational Safety,Institute of Occupational Safety and Health,Council of Labor Affairs Department of Health and Nutrition Biotechnology,Asia University,Taichung,Taiwan 41354,,China Department of Safety Health and Environmental Engineering,National United University,Miaoli,Taiwan,C

会议类型: 国际会议

会议名称: 2012 International Symposium on Safety Science and Technology (2012安全科学与技术国际会议)

会议地点: 南京

会议语种:英文

页码: 523-525

在线出版日期: 2012-10-23（万方平台首次上网日期，不代表论文的发表时间）