Synthesis and Characterization of Hierarchical ZSM-48 zeolite

摘要：

　　A series of hierarchical ZSM-48 zeolites was prepared by seed silanization.The structural and textural properties of the hierarchical ZSM-48 were characterized by X-ray diffraction (XRD),scanning electron microscope (SEM),transmission electron microscope (TEM),N2 adsorption-desorption,27Al and 29Si magic angle spinning nuclear magnetic resonance (MAS NMR),and Fourier transform infrared spectroscopy adsorbed by pyfidine (Py-IR).It was found that the crystal size of ZSM-48 was significantly reduced by seed silanization.Due to the secondary porosity in the mesopore region generated in hierarchical ZSM-48,both the total surface area and the pore volume of the material have a considerable increase.The enhancement of the textural properties could be controlled by changing the amount of silanizaiton agent.

关键词： ZSM-48 zeolite hierarchical porous silanization

作者: Xiaoling Liu Xujin Wang Yan Wang Yanjun Gong Tao Dou

作者单位: State Key Laboratory of Heavy Oil Processing,The Key Laboratory of Catalysis of China National Petroleum Corporation,China University of Petroleum-Beijing,Changing Beijing,102249,China

会议类型: 国际会议

会议名称: the 2012 2nd International Conference on Frontiers of Manufacturing Science and Measuring Technology (第二届制造科学与检测技术国际会议(ICFMM 2012))

会议地点: 西安

会议语种:英文

页码: 756-759

在线出版日期: 2012-06-12（万方平台首次上网日期，不代表论文的发表时间）