Preparation and Binding Characteristics of Molecularly Imprinted Polymers for Capsaicin
To isolate capsaicin effectively,molecular imprinted polymers (MIPs) with capsaicin were synthesized with methacrylicacid (MAA) as function monomers,ethyleneglycol dimethacrylate (EGDMA) as cross linker by non-covalent method.Technological parameters for the preparation of MIPs were optimized by L9(34) orthogonal test.The static equilibrium binding and recognition properties of MIPs to capsaicin were also investigated.The surface structure of the MIPs was visualized by scanning electron micrography.The results show that the optimistic composition of MIP is as following:0.25 mmol capsaicin,7.0 mL acetonitrile,3.0 mL ethylether,1.25 mmol MAA and 100 μL 80% tween-80.The adsorption isotherms indicates that the MIPs show a good imprinting effect (QMIPs=23.44 mg/g).The MIPs have the specific recognition selectivity for capsaicin in the mixture.Thus,compared with zingerone and piperine which are similar in molecular structure and property to capsaicin,the MIPs show a good selectivity and intense recognition of the template molecule.
Capsaicin Molecular imprinted polymers Adsorption selectivity
Jing Sun Ning Peng Wenxiang Ao Xuesong Huang
Department of Food Science and Engineering, Jinan University, Guangzhou 510632, China
国际会议
厦门
英文
582-585
2012-01-04(万方平台首次上网日期,不代表论文的发表时间)