The Research of Gas-sensing and Optical Characterization of Chlorinated Metallic Porphyrin Spin-coated Films
In this text,the Chlorinated metallic porphyrin (TPPMncl and TPPFecl) thin films were fabricated by Spin-coated technique onto quartz substrates.In order to search for the gas-sensing characterization of Chlorinated metallic porphyrin Spin-coated films,the changes of UV-Visible absorption spectrums of TPPMncl and TPPFecl Spin-coated films respectively exposed in vapor of Chloroform,pyridine,Ammonia,triethylamine and dimethylamine were analyzed.The experimental results show that,the spectral response of TPPMncl and TPPFecl on organic gas molecular is obviously found.And we know that chlorinated metallic porphyrin film formed the J-aggregates.Moreover,through two kinds of chlorinated metallic porphyrin integral area rate of histogram,it is easy to identify and distinguish between the four kinds of volatile organic compounds.It indicates that these Chlorinated metallic porphyrin have gasochromic characteristics while responding with organic gas.Therefore,these materials can be prepared into gas sensor array for detecting VOCS.
Chlorinated metallic porphyrin UV-VIS Gas-sensing characterization Volatile organic compounds Spin-coated technique
Wen Yao Yang Jian Hua Xu Si Yu Wang Yan Chen
State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Optoelectronic Information, University of Electronic Science and Technology of China(UESTC), Chengdu 610054,P.R.China
国际会议
广州
英文
58-62
2012-11-16（万方平台首次上网日期，不代表论文的发表时间）