Study on novel structure of Mn-Di(3,4,6,7-tetramethyl-1,10-phenanthroline) dichloride:Mn(C16H16N2)2·Cl2
Metal complexes containing diimine ligands such as 1,10-phenanthroline and bipyridine are very important and widely used in analytical chemistry,catalysis,electrochemistry,ring-opening metathesis polymerization and biochemistry.1,10-phenanthroline,which is the parent for important class chelating agents,has been widely used in the construction of supramolecular architectures.Lots of phenanthroline and its derivatives complex have been synthesized and reported.In the paper,a novel Mn and 3,4,6,7-tetramethyl-1,10-phenanthroline complex Mn(C16H16N2)2·Cl2 has been synthesized from a solution reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction.Mn(C16H16N2)2·Cl2,Orthorhombic,Pnna.a =8.8376(8)(A) b =18.3630(17)(A) c =18.0159(18)(A) α=β=γ=90°.V=2923.7(5)(A)3.Z=4.Rgt(F) =0.0341,wRref(F2) =0.0958.T=273(2) K.The novel Mn metal complex structure is explained clearly.
Mn metal complex structure analysis Phenanthroline
Hai Xing Liu Huan Mei Guo Jing Zhong Xiao Guang Zeng Hui Juan Yue Xi Shi Tai
College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, P.R.China Department of Physics, University of Coimbra, Coimbra 3004-516, Portugal State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University,Changchun 13
国际会议
广州
英文
413-416
2012-11-16（万方平台首次上网日期，不代表论文的发表时间）