Study on novel structure of glycolic and oxalic acid holmium:Ho(C3H6O9)·CH3OH
In the study of functional materials,more attention is the construction of organic-inorganic hybrid materials with structural diversity,fascinating properties,and potential applications in catalysis,molecular adsorption,medicine,electro-conductivity,magnetism and photochemistry.At present,the research work in upconversion emission in rare-earth doping materials has been greatly increased.Yb3+ and Ho3+ upconversion energy transfer is attractive,because Yb3+ and Ho3+ upconversion energy transfer is relatively simple compared to upconversion involving other rare-earth ions.In this paper,a novel holmium complex Ho(C3H6O9) ·CH3OH has been synthesized from a hydrothermal reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction.The Ho atom is coordinated by eight O atoms.The molecular is antisymmetric structure by the C2-C2 axis.The molecular structure stabilized by the O-H(...)O hydrogen-bonding interactions.
Holmium Complex Structure Analysis Materials
Hai Xing Liu Wu Lan Zeng Jing Zhong Xiao Guang Zeng Hui Juan Yue Xi Shi Tai
College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, P.R.China Department of Physics, University of Coimbra, Coimbra 3004-516, Portugal State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University,Changchun 13
国际会议
广州
英文
417-420
2012-11-16(万方平台首次上网日期,不代表论文的发表时间)