The synthesis of 3D open framework nano-scale zinc phosphite

摘要：

　　By employing 1,4-diazabicyclo2.2.2octane (DABCO) as pillared ligand,a new 3D nano-scale zinc phosphite Zn3(C6H12N2)2(HPO3)3 has been solvothermally prepared.Its structure is constructed of neutral zinc phosphite layers,which are composed of ZnO3N tetrahedral,ZnO3N2 trigonal bipyramidal and HPO3 pseudo-tetrahedral.The inorganic layers pack in an ABAB sequence with the DABCO ligands as pillars,thus generating a 3D framework.It is worth noting that the title compound exhibits 1D hexagonal 12-MR channels with extra-large pore (diameter about 1.0 nm × 1.0 nm).Topological analysis shows that the title compound is an unprecedented 3,4,5-connected network.

关键词： Nano-scale open-framework zinc phosphate

作者: Jian qiao Teng Jiawei Wang Zheming Xu Hualong Liu Yunling Yang Weimin

作者单位: Shanghai Research Institute of Petrochemical Technology Shanghai 201208; Fudan University, 200433 Shanghai Research Institute of Petrochemical Technology Shanghai 201208 Fudan University, 200433 Jilin University, 130021

会议类型: 国际会议

会议名称: 2012 Postdoctoral Symposium of China on Materials Science & Engineering -- Advanced Materials for Sustainable Development (2012 年中国博士后材料科学与工程学术论坛--先进材料与可持续发展)

会议地点: 上海

会议语种:英文

页码: 68-68

在线出版日期: 2012-10-19（万方平台首次上网日期，不代表论文的发表时间）