Interfacial assembly and supramolecular chirality of a series of Cu(Ⅱ)-coordinated Schiff bases complexes
Four achiral Cu(Ⅱ)-coordinated Schiff bases complexes containing aromatic structures were synthesized and their supramolecular assemblies at the air/water interface were investigated.All compounds could be spread on water surface although they have no alkyl chains.The Schiff base complex molecules with naphthyl groups formed J-aggregate in the LB films transferred from water surface.In AFM,a multilayer film or three-dimensional structures was observed.It is interesting to note that the LB films of achiral Cu-NA transferred from water surface showed chirality.The supramolecular chirality in these LB films was suggested to be due to a cooperative stereoregular stacking of the functional groups in a helical sense.This research work provides a helpful clue for regulating the nanostructures and supramolecular chiral assembly in organized films.
Interfacial assembly langmuir-blodgett film supramolecular chirality schiff base
Jiao Tifeng Li Xuhui Zhang Qingrui Zhang Li Liu Minghua Li Qiurong Zhou Jingxin Gao Faming
Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface Scie
国际会议
上海
英文
124-124
2012-10-19（万方平台首次上网日期，不代表论文的发表时间）