Synthesis and Chiral Recognition Ability of Optically Active Polymethacrylamides

摘要：

　　The radical polymerization of an optically active methacrylamide,N-(L)-a-anilinecarbonylbenzyl methacrylamide (ACBMAM),was carried out in the absence and presence of Lewis acids.The specific rotations of the obtained polymers varied with the tacticities,suggesting that the tacticities influence the secondary structures of the polymers.The chiral recognition abilities of the optically active polymers immobilized on silica gel was evaluated as the chiral stationary phase for high-perforrnance liquid chromatography.

关键词： radical polymerization Lewis acid chiral tacticity

作者: Ruiqi Li Xinghua Hu Jiani Li Yang Li

作者单位: College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin, P.R.China

会议类型: 国际会议

会议名称: The 5th Symposium on Molecular Chirality of Chinese Chemical Society & International Chiral Meeting (中国化学会第五届全国分子手性学术研讨会暨国际手性会议(5th MCCCS & ICM))

会议地点: 张家界

会议语种:英文

页码: 76-77

在线出版日期: 2012-08-01（万方平台首次上网日期，不代表论文的发表时间）