Study on Steam Catalytic Reforming of the Mixed Types of Bio-oil Model Compounds for Hydrogen Production
The substances like acetic acid,furfural,glycerol,acetone and phenol were selected and used with uniform mixture of equal quality of bio-oil model compounds.Coal ash used as a carrier,two kinds materials of nickel-based catalysts were prepared by impregnation method.Conditions and rules of hydrogen production was studied in the steam catalytic reforming atomized in a fixed bed reactor.The experiments showed CuO added in the catalyst of Ni/coal ash could reduce the carbon deposition speed,and improve the catalytic activity.In order to study the reforming of the mixed types of bio-oil model compounds into hydrogen by steam catalysis,Ni/CuO-coal ash was chosen as catalyst to produce of H2,CO,CH4 and CO2.The optimum reaction condition was obtained as follow:reaction temperature is 650~600 C,S/C is 10~14 and feeding flow rate is 6~8g/min.
component bio-oil model compound catalytic reforming hydrogen production fixed bed gasification
CHEN Mingqiang ZHANG Peng LIU Shaomin WANG Jun YANG Zhonglian WANG Hua
Department of Chemical Engineering, Anhui University of Science Technology, Huainan 232001, China
国际会议
合肥
英文
195-199
2012-05-24（万方平台首次上网日期，不代表论文的发表时间）