Synthesis and Standard Molar Formation Enthalpy of plate shape NaZnPO4·H2O

摘要：

　　Plate shape NaZnPO4·H2O was synthesized by solid-state reaction at low temperature and characterized by X-Ray Diffraction,Scanning electron microscope and elemental analysis.Thermochemical study was performed with an isoperibol solution calorimeter.Based on Hesss law,thermochemical cycl was designed to determine the dissolution enthalpies of reactants and products using a solution-reaction isoperibol calorimeter at 298.15 K,and the molar reaction enthalpy was calculated on the basis of above dissolution enthalpies.The results show that the obtained product is plate shape NaZnPO4·H2O.The standard molar formation enthalpy of the NaZnPO4·H2O is AfHm(⊙)NaZnPO4·H20,s=-1967.18 ± 0.69 kJ·mol-1.

关键词： Sodium zinc phosphate Solid-state reaction at low temperature Standard molar formation enthalpy

作者: Shao-mei Ma Sheng-fu WU Zeng-wei Huang An-ping Liao Ai-qun Yuan

作者单位: College of Chemistry and Ecology Engineering, Guangxi University for Nationalities, keylaboratory of College of pre-education, Guangxi University for Nationalities, Nanning Guangxi,530006,China

会议类型: 国际会议

会议名称: the Second International Conference on Frontiers of Manufacturing and Design Science(第二届制造与设计科学国际会议(ICFMD 2011))

会议地点: 台湾

会议语种:英文

页码: 175-180

在线出版日期: 2011-12-11（万方平台首次上网日期，不代表论文的发表时间）