Thermal Stability and Structure of Tellurite Glass
Oxyfluoride tellurite glass with the composition of TeO2-AlF3-LaF3-ZnO/ZnCl2/ZnF2 was prepared successfully.The thermal stability and structure of TeO2-AlF3-LaF3 system tellurite glass were studied by DSC and IR spectra.The results indicated that glass transition temperature of TeO2-AlF3-LaF3-ZnO/ZnCl2/ZnF2 glass was higher than that of (1-x)TeO2-xAlF3 (x=10%,20%,30%,40%,50%,in mol%) binary glass system slightly.A small number of ZnF2/ZnCl2/ZnO (5mol%) improved glass thermal stability.After adding 5mol% ZnF2/ZnO/ZnCl2 into fluoride tellurite glass respectively,glass transition temperature increased in turn.The introduction of 5mol% different zinc compounds had a little impact on the glass network structure.
Oxyfluoride tellurite glass Thermal stability Glass network structure
Zhaoxia Hou Zhaolu Xue Shaohong Wang Xiaodan Hu Haoran Lu Changlei Niu Hao Wang Cai Wang Yin Zhou
Liaoning Province Key Laboratory of Advanced Materials Technology,Shengyang University,Shengyang 110044,China
国际会议
The Seventh China International Conference on High-Performance Ceramics (第七届先进陶瓷国际研讨会(CICC-7))
厦门
英文
994-997
2011-11-04(万方平台首次上网日期,不代表论文的发表时间)