XPS Studies on ZrO2 Thin Films Deposited on Glass Substrate by Sol-Gel
The chemical composition and the valence state of elements on the surface of ZrO2 thin films deposited on glass substrates have been studied by X-ray photoelectron spectroscopy.Results show that:elements ofNa,Mg,Zr,Ca exist in the form of their respective stable state,such as Na2O,MgO,ZrO2,CaO,when heat treated at 500℃ for 0.5h; but Si is unstable,and exhibit stoichiometrical disturbances.Results of chemical composition and their content by atom percent of ZrO2 thin films surface reveal that:Si,and Ca diffuse from glass to the thin films in scale; Na diffuses few and Mg collects to the thin films surface.The diffusion of Mg2+ and Ca2+ from glass to ZrO2 thin films is negative diffusion.
XPS ZrO2-CeO2 thin films Sol-gel
Xingang Yu Yi Gong Wenyue Bi Xuechun Tian Hongwen Ma Huifeng Zhao Guohong Qiu Li Wang
College of Materials Science and Engineering,Chongqing University,Chongqing,400044,China Department of Material Science,China University of Geosciences Beijing,100083,China Research Institute of Glass and Glass Fiber,China Building Materials Academy Beijing,100024,China
国际会议
The Fifth China International Conference on High-Performance Ceramics (第五届先进陶瓷国际研讨会(CICC-5))
长沙
英文
1277-1279
2007-05-10(万方平台首次上网日期,不代表论文的发表时间)