Preparation and Thermoelectric Properties of Polyaniline doped with Protonic Acids

摘要：

　　Hydrochloric acid doped polyaniline and camphor sulfonic acid doped polyaniline were prepared by oxidative chemical polymerization and grinding,respectively.The structures of polyaniline samples were measured by Fourier transform infared spectroscopy.The Seebeck coefficient and electrical conductivity of the composites were investigated as protonic acid content in the temperature range from room temperature to 380K.The highest electrical conductivity of the 1M hydrochloric acid doped polyaniline reaches 5.57×102S/m at 320K,and the mass ratio of 1:1 camphor sulfonic acid doped polyaniline reaches 5.97×102S/m at 380K.This work suggests that a new method improves the thermoelectric properties of conducting polymers.

关键词： Polyaniline Protonic acids-doping Thermolelectric property

作者: Qingli Zhang Yanxia Chang Lianjun Wang Wan Jiang

作者单位: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Donghua University, 2999 North Renming Road, Shanghai 201620, China

会议类型: 国际会议

会议名称: the Chinese Materials Congress 2012(2012年中国材料大会(CMC2012))

会议地点: 太原

会议语种:英文

页码: 100-104

在线出版日期: 2012-07-13（万方平台首次上网日期，不代表论文的发表时间）