Synthesis and Crystal Structure of Phosphorus Vandium Heteropolyacid Sodium

摘要：

phosphorus vandium heteropolyacid sodium, H78N12NaO116P2V30, is prepared by the hydrothermal method. Cubic, Fm-3m. a =b = c = 20.022(2) (A) α=β=γ= 90°. V= 10680.0(17) (A)3. Z=4. R1 =0.0388, wR2 = 0.1200. T=298(2) K. The V atoms are linked with O atom bridge. The molecular structure is stabilized by the O-H...O and O-H...N intermolecular and intramolecular hydrogen-bond interaction.

关键词： Vandium Heteropolyacid Structure Analysis Hydrogen-Bond Interaction

作者: Haixing Liu Jingzhong Xiao Jing Wang Fangfang Jian Huijuan Yue Xishi Tai

作者单位: College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, China Department of Physics, University of Coimbra, Coimbra 3004-516, Portugal New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Techno State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, JilinUn

会议类型: 国际会议

会议名称: 2012 International Conference on Advanced Materials Design and Machanics(2012先进材料设计与机械学国际会议 ICAMDM 2012)

会议地点: 厦门

会议语种:英文

页码: 103-106

在线出版日期: 2012-06-05（万方平台首次上网日期，不代表论文的发表时间）