ACTIVE CATHODE OF LITHIUM BATTERY FOR ELECTRIC VEHICLE
Lithium manganese oxides with a fine spherical morphology different from that of the normal composite oxides are formed after detonation wave treatment due to the very high quenching rate.Free metal atoms are first released with the decomposition of explosives,and then theses metal and oxygen atoms are rearranged,coagulated and finally crystallized into lithium manganate during the expansion of detonation process.The growth of lithium manganate via detonation reaction was investigated with respect to the presence of an energetic precursor,such as the metallic nitrate and the degree of confinement of the explosive charge.The detonation products were characterized by scanning electron microscopy.Powder X-ray diffraction and transmission electron microscopy were used to characterize the products.Lithium manganate with spherical morphology and more uniform secondary particles,with smaller primary particles of diameters from 10 to 20 nrn and a variety of morphologies were found.
Explosives detonation nanometer oxides
X.H.Xie S.Y.Liu J.Xie M.C.Yin S.L.Yan
School of Chemical Engineering,Anhui University of Science and Technology,Huainan,Anhui 232001,China School of Journalism,Fudan University of Science and Technology,Room 606,Building 17, GuoDing Road 4
国际会议
The Third International Conference on Heterogeneous Material Mechanics(第三届国际非均匀材料力学会议)
上海
英文
100-103
2011-05-22（万方平台首次上网日期，不代表论文的发表时间）